Enhanced modified Magnetite Bentonite-CaO/FeCl3 from solid waste for highly efficient Methylene blue removal

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Yudha Gusti Wibowo, Hana Safitri, Kholivia Cahyani, Arif Rohman, Sudibyo, Ahmad Tawfiequrahman Yuliansyah, Himawan Tri Bayu Murti Petrus, Setyo Budi Kurniawan, Bimastyaji Surya Ramadan, Anis Tatik Maryani, Hutwan Syarifuddin

2025 Global Nest Journal Vol. 27 Issue 4 Article Cited by 3 Quartile

Abstract

This study focuses on the development and evaluation of novel materials bentonite-CaO, magnetite bentonite-FeCl3, and magnetite bentonite-CaO/FeCl3 as potent adsorbents for the removal of methylene blue dyes from aqueous solutions. Batch adsorption test was conducted with variations of contact times and dye concentrations. The maximum sorption capacity reached 39 mg/g with Langmuir isotherm model (R2 =0.999) following the pseudo second-order kinetic model. The materials exhibited exceptional effectiveness, achieving a remarkable 99% reduction in methylene blue concentration within an astonishingly short 10-minute duration. Additionally, this study provides valuable insights into the potential applications of these modified adsorbents in environmental remediation, accompanied by practical recommendations for their utilization in various scenarios. © 2024 Global NEST Printed in Greece. All rights reserved.

Affiliations

Sustainable Mining and Environmental Research Group, Department of Mining Engineering, Institut Teknologi Sumatera, Lampung, 35365, Indonesia; Sustainable Mineral Processing Engineering, Department of Chemical Engineering, Universitas Gadjah Mada, Yogyakarta, Indonesia; Center for Green and Sustainable Materials, Institut Teknologi Sumatera, Lampung, 35365, Indonesia; Department of Geomatic Engineering, Institut Teknologi Sumatera, Lampung, 35365, Indonesia; Research Center for Mining Technology, National Research, and Innovation Agency, Lampung, 35361, Indonesia; Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, UKM, Selangor, Bangi, 43600, Malaysia; Department of Environmental Engineering, Universitas Diponegoro, Semarang, Indonesia; Postgraduate Program of Environmental Science, Universitas Jambi, Jambi, Indonesia