Adsorptive removal and photocatalytic decomposition of cationic dyes on niobium oxide with deformed orthorhombic structure

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Tarmizi Taher, Akihiro Yoshida, Aldes Lesbani, Irwan Kurnia, Guoqing Guan, Abuliti Abudula, Wataru Ueda

2021 Journal of Hazardous Materials Vol. 415 Article Cited by 46 SDG 17SDG 14SDG 6SDG 12 Quartile

Abstract

Nano-rod-shaped niobium oxide with a deformed orthorhombic structure (ortho-Nb2O5) is first demonstrated as a selective adsorbent to remove cationic dyes wastewater. Ortho-Nb2O5 quickly adsorbs methylene blue (MB) with much greater capacity than reported inorganic adsorbents. Furthermore, ortho-Nb2O5 has a stronger affinity to cationic dye than anionic dye because cation exchange is involved in the adsorption process. The dye molecule adsorbed onto ortho-Nb2O5 can be degraded entirely under UV light irradiation because of its photocatalytic properties. Moreover, the regenerated ortho-Nb2O5 shows high reusability for use in additional adsorption processing. As described herein, new insights into the use of ortho-Nb2O5 as a photocatalytically regeneratable adsorbent for wastewater treatment are presented. © 2021 Elsevier B.V.

Affiliations

Institute of Regional Innovation, Hirosaki University, 2-1-3 Matsubara, Aomori, 030-0813, Japan; Department of Environmental Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu, Way Hui, Kecamatan Jati Agung, Lampung Selatan, 35365, Indonesia; Graduate School of Science and Technology, Hirosaki University, 1-Bunkyocho, Hirosaki, 036-8560, Japan; Department of Environmental Sciences, Graduate School of Sriwijaya University, Jl. Padang Selasa, No. 524, Bukit Besar, Palembang, 30139, South Sumatra, Indonesia; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih, Km. 32, Ogan Ilir, 30662, South Sumatra, Indonesia; Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama, 221-8686, Japan

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