Adsorptive Performance of Congo Red using Copper-Aluminum LDHS Load to Rice Husk Biochar; [Prestasi Penjerapan Kongo Merah menggunakan Beban Tembaga-Aluminium LDHS kepada Bioarang daripada Sekam Padi]

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Neza Rahayu Palapa, Novie Juleanti, Normah, Tarmizi Taher, Risfidian Mohadi, Addy Rachmat, Aldes Lesbani

2022 Sains Malaysiana Vol. 51 Issue 1 Article Cited by 9 SDG 17SDG 12SDG 6 Quartile

Abstract

This work aimed that CuAl layered double hydroxide (LDH) is loaded to biochar to form CuAlLDH@BC composites by co-precipitation methods. CuAlLDH@BC composite was prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, surface area specific analysis BET method, thermalgravimetric, and scanning electron microscopy (SEM) for morphological analysis. CuAlLDH@BC composite used as adsorbent for the removal of Congo red. The adsorption ability of CuAlLDH@BC composite evaluated by pseudo-second-order kinetic model, with Qecalculated and Qeexperimental of the composite were closed (47.619 and 46.143 mg/g, respectively). Furthermore, the adsorption conducts were more consistent with the Langmuir isotherm model, than the Freundlich isotherm model. The isotherm adsorption data obtained the maximum adsorption capacity was 61.350 mg/g. Thermodynamic studies illustrated the endothermic nature of CuAlLDH@BC, as well as the fact that the adsorption process is spontaneous. Thus, CuAlLDH@BC showed a high reusability performance even after third cycle of adsorption-desorption process. © 2022 Penerbit Universiti Kebangsaan Malaysia. All rights reserved.

Affiliations

Graduate School, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang-Prabumulih, Km. 32 Ogan Ilir, South Sumatera, Indonesia; Research Center of Inorganic Materials, Complexes Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa Bukit Besar, South Sumatera, Palembang, 30139, Indonesia; Department of Environmental Engineering, Institut Teknologi Sumatera Jalan Terusan Ryacudu, Way Hui Kecamatan Jati Agung Lampung Selatan, 35365, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang-Prabumulih, Km. 32 Ogan Ilir, South Sumatera, Indonesia

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