Insight into the pyrolysis behavior of the drained Sumatra peat soil and the characteristics of the resulting biochar for carbon dioxide (CO2) capture

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Tarmizi Taher, Raden Putra, Novi Kartika Sari, Alfian Zurfi, Arif Rohman, Irwan Kurnia, Sena Maulana, Kartika Kartika, Yudha Gusti Wibowo, Aditya Rianjanu, Aldes Lesbani

2023 Bioresource Technology Reports Vol. 24 Article Cited by 14 Quartile

Abstract

This study investigated the potential of drained Sumatra peat soil (SPS) as a feedstock for pyrolysis to produce biofuels and biochar. We used thermogravimetry analysis (TGA), evolved gas analysis coupled with mass spectroscopy (EGA-MS), and pyrolysis-gas chromatography-mass spectroscopy (Py-GCMS) to study the decomposition behavior of SPS and pyrolysis product distribution. We also characterized the biochar (PBS) and assessed its CO2 adsorption capacity. The results reveal that the organic content of SPS can be fully pyrolyzed at temperatures above 500 °C, leaving about 18 wt% of inorganic residues. The pyrolysis process mainly produces hydrocarbons, alcohols, phenols, and acids products, depending on operating temperatures. The biochar has distinct physical and chemical properties and shows remarkable CO2 adsorption capabilities and reusability, where its adsorption capacity is maintained even after six adsorption-desorption cycles. Thus, SPS can be used as a feedstock for biomass-to-energy conversion and biochar creation through pyrolysis, reducing atmospheric carbon levels from peatland degradation. © 2023 Elsevier Ltd

Affiliations

Department of Environmental Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung Selatan, Way Hui, Indonesia; Department of Geomatics, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung, Way Hui, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjajaran, Jl. Raya Bandung – Sumedang KM 21 Jatinangor,West Java, Sumedang, Indonesia; Department of Forestry Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung, Way Hui, Indonesia; Research Center for Biology, Research Organization for Life Sciences, National Research and Innovation Agency (BRIN), West Java, Cibinong, 16911, Indonesia; Department of Mining Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung, Way Hui, Indonesia; Department of Material Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung, Way Hui, Indonesia; Graduate School of Mathematics and Natural Sciences, Sriwijaya University, Sumatera Selatan, Indonesia; Center for Green and Sustainable Materials, Institut Teknologi Sumatera, Jalan Terusan Ryacudu,Lampung, Way Hui, Indonesia; Department of Chemical Engineering, Universitas Gadjah Mada, Daerah Istimewa Yogyakarta, Yogyakarta, 55281, Indonesia